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Think of the 220EX as just a extension of your build in flash. You will see that only the 220EX will function and not the internal flash. That is correct because the G7 knows the 220EX is fitted and therefore disabled the internal flash.
With your G7 in Auto Mode you can now try a few pictures. Use the G7 inside the house, take pictures of the family, the dog and the furniture. Also go outside in daylight and again take a number of different pictures to see how the combo works. You will notice that the shutter speed is always 1/60 seconds and the aperture is always at its largest setting, for example f2,8 at minimum zoom. On a bright sunny day you will see that the shutter speed (Tv) will increase to a maximum of 1/250. You will also notice that the flash is permanently on and it is not possible to cancel or switch off the flash. On the back of the 220EX you will see a flash OK indication. Important is to check this indicator after each picture you take. The flash OK lamp goes on when the exposure was good based on the ETTL-L measurement. If not then the flash OK indication will stay off.
Instead of using auto Mode, my advice is to use P-Mode. P-mode is the same as auto mode but with a few additional features available to the photographer. With P-Mode selected you will have the following additional functionality:
High Speed Sync (FP Flash) allows you to increase the shutter speed to more than the maximum 1/250. Best way to try this is to go outside on a bright sunny day and to take a few pictures with the 220EX fitted. You will see that the flash is always on and that the exposure is measured as if the flash is not mounted. This is interesting as normally with a flash mounted one would see a aperture of 2,8 and a shutter speed of 1/60. The FP Flash function allow the G7 to act normal as if no flash is mounted. The are photographers who permanently leave their flash unit on the camera and switched on in the FP mode, especially during outside photography. Try it, you will be surprised to see how difficult outside areas, change into fun areas to photograph. For example this setting will allow for good fill flash plus good surroundings exposure. I did not find any clear description or setting to activate this function on the G7 internal flash only. To enable high speed sync on the G7 build in flash you select the Tv Mode. This enables you to select the shutter speed you like to have, also faster than the normal 1/250.
Flash Exposure Lock (FE Lock) is a handy way of pre-determining the correct exposure prior to taking the picture. Hold the G7 up and press the (*) FE button. You will see the G7 doing a pre-flash to measure the flash exposure and the exposure is then displayed on the bottom of the G7 screen. The G7 is now ready to take the picture. Often it is difficult to get the correct exposure outside. One way of measuring the exposure is to point the G7 down to a cement footpath or to green grass and to do a exposure lock on that area, then to lift the camera and to then take the picture. With this method you can fix a exposure, then differently fix the focus and then take the picture in the frame you wanted to. Alone with this function you have a lot of creativity and flexibility.
Exposure and flash compensation is also available when P-Mode is selected. With the G7 and the 220EX you can adjust both the flash output and the exposure. To better understand this functionality it is best is to experiment with these settings. Find a appropriate place outside with a dark area in front of you and with a bright blue sky line. Normally when you lift the G7 with flash mounted then the darker area in front will be good but the skyline will be over exposed. To prevent that from happening you can do exposure compensation, one for the skyline and one for the flash. The skyline or exposure compensation is done via the outside button, right above the adjustment wheel on the back of the G7 and the flash exposure compensation is done on the MyColors menu.
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